Fabian Mohn, Leo Gross, et al.
Nature Nanotechnology
A covalent bond between an individual pentacene molecule and a gold atom was formed by means of single-molecule chemistry inside a scanning tunneling microscope junction. The bond formation is reversible, and different structural isomers can be produced. The single-molecule synthesis was done on ultrathin insulating films that electronically isolated the reactants and products from their environment. Direct imaging of the orbital hybridization upon bond formation provides insight into the energetic shifts and occupation of the molecular resonances.
Fabian Mohn, Leo Gross, et al.
Nature Nanotechnology
Lisanne Sellies, Jakob Eckrich, et al.
Nature Nanotechnology
Shadi Fatayer, Nimesh B. Poddar, et al.
JACS
Niko Pavliček, Przemyslaw Gawel, et al.
Nature Chemistry